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Harnessing formate as a CO2 surrogate for chiral β-hydroxy acid synthesis by photoredox hydrocarboxylation of alkenyl acetates. the-innovation.org/article/d…
New in The Innovation Life! Harnessing formate as a CO2 surrogate for chiral β-hydroxy acid synthesis by photoredox hydrocarboxylation of alkenyl acetates. Xia et al. have developed a chemo-enzymatic cascade system that harnesses photoenergy to transform a fundamental C1 building block. @InnovationLife doi.org/10.59717/j.xinn-life… #photocatalysis #greenchemistry
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New in The Innovation Life! Harnessing formate as a CO2 surrogate for chiral β-hydroxy acid synthesis by photoredox hydrocarboxylation of alkenyl acetates. Xia et al. have developed a chemo-enzymatic cascade system that harnesses photoenergy to transform a fundamental C1 building block. @InnovationLife doi.org/10.59717/j.xinn-life… #photocatalysis #greenchemistry
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Newest addition to the Frank Thomas PC! Love the acetates #PC #cards #frankthomas
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Rare David Bowie & Dana Gillespie “Bowpromo” White Label 12" Vinyl Up for Auction A truly exceptional piece of early David Bowie history is currently featured in Heritage Auctions: a rare white label promotional 12" vinyl record featuring David Bowie and Dana Gillespie, housed in a plain white sleeve. Item Highlights Artist: David Bowie & Dana Gillespie Format: White Label Promo 12" Vinyl Record Title: Bowpromo (rare early promotional release) Sleeve: Plain white sleeve Auction: Heritage Auctions (Lot in current/upcoming sale) This white label promo dates back to Bowie’s early 1970s period and is highly sought after by collectors due to its rarity and connection to his pre-fame collaborations. Dana Gillespie was a close associate of Bowie during his early career, and these kinds of promotional acetates/white labels are extremely scarce. Items like this offer a fascinating glimpse into the pre-Ziggy Stardust era and Bowie’s rapid rise in the music industry. Original Source: David Bowie, Dana Gillespie entertainment.HA.com/itm/mus… David Bowie, Dana Gillespie BOWPROMO White Label 12" Vinyl Record with White Sleeve. Vintage original 12" vinyl demo used to secure new record deals for David Bowie and Dana Gillespie. Only 500 were pressed by Bowie and Gillespie's manager Tony Defries, with white labels and white sleeves. Like the other 499 made, this disc has "BOWPROMO 1A - 1" and "BOWPROMO 1B - 1" stamped in the respective sides' runout grooves. One side has seven songs from Bowie, (5) of which ended up on the original release ofHunky Dory("Oh! You Pretty Things", "Eight Line Poem", "Kooks", "Queen Bitch", and "Quicksand") while (1) song was onThe Rise and Fall of Ziggy Stardust and the Spiders from Mars("It Ain't Easy") and (1) song was a bonus track on the 1990 reissue onHunky Dory("Bombers"). The other side of this disc has (5) songs by Gillespie ("Mother Don't Be Frightened", "Andy Warhol", "Never Knew", "All Cut Up On You" and "Lavender Hill"). Both Bowie and Gillespie ended up on RCA Records. The blank white sleeve is in VG 5.5 condition and the disc is in EX 7 condition. There is handwriting on both labels denoting "David Bowie / Hunky Dory" (including "1" on one side), but most of the writing has been removed.Comes with a COA
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Drubble four you soon knee be, Linking triangle grinder shover see, Shrivel up your little aggregates, Im sifting through them wide awake. Bake my cake and candles great, Shredding cheeses sticks on stake, Head first this time into my minds, Curtain coke plain my shotgun frame. Lore of things yet I clip the wings, See what my men card ace can bring, Extra fun for the pokies much, Moneys irrelevant, broke legs crutch. Swing my fingers out to crum, But my cigar out in your face of none. Maybe I’ll push it until garbage come, I got no singles and know number one. Top chart smash rap excel of a eights, Levitating head boy head trip X-ray 8. Dishing soup can broom on wakes, Sea salt burner twist pepper shakes, Season all for my my might brawls, Pelican pub boy or flamingos crawls. Pinch the shell or the ghost from hell, What can you smell, is it fear, as well? I got the sugar and the drink to match, Flicking your acetates mash to breaks Cripple your legwork and broken neck Pick you up again, and poke, you heck! Before this was, what of it is all is, Listing a side link and ride the fist. So watch yourself and you hands of to Come too close, and it is overs the two Candlesticks, and your ancient tricks, Moon jump over, and jack of backflips.
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I love those too, I pulled 2 acetates from the Marvel anime yesterday.
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organic-chemistry.org/abstra… A centrally chiral pyridoxal catalyst mediates a direct enantioselective α-C allylic alkylation of N-unprotected α-substituted amino esters with MBH acetates.
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organic-chemistry.org/abstra… An efficient two-step protocol that employs readily available terminal alkenes as starting materials enables a highly regio- and stereoselective synthesis of various allylic acetates.
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UNCUT 1st September 2022 WHEN Chris Stein moved out of Manhattan around 20 years ago, he took several boxes of Blondie ephemera with him and stored them in his garage. These included a backstage mirror from Hammersmith Odeon that was hauled back to America like Viking plunder, as well as approximately 100 water-damaged reels of unreleased music, acetates, vinyl and home-recorded cassettes. Some came from the very start of the band's career in 1974, when Stein and Debbie Harry live together in a succession of crummy New York apartments. Others were experimental remixes, created in 1982 as the band fell apart. In between were the origins of most of Blondie's biggest hits. Did Harry have any idea of what her bandmate was sitting on? Debbie Harry: "I know he is a very good collector and he always kept very interesting things. It's been a while since we lived together, but I knew that anything he recorded at home or in his own studio would be there. There's all the stuff we recorded together, home demos. Chris had his own label, Animal, so it's all that stuff too." 🌎🚨🎹🪩👄🗽🔥🧷🎤🌊🎧🎸🪇🥁
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Sterically Tolerant Nickel-Catalyzed Borylation of Aryl Triflates, Vinyl Triflates, and Vinyl Acetates ( @JOC_OL ): pubs.acs.org/doi/10.1021/acs….
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@CardPurchaser well… I’m definitely taking my boys kid with me again tomorrow to card hunt.. 🔥🔥🔥 Both acetates were stuck together
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Replying to @drjohnm
While it's on the physicians to ensure the accuracy of their papers and slides, not adopting AI would be equivalent to continuing to ride a horse when there is an automobile, handwrite when there is a typewriter, and use acetates when there is a projector. I believe strongly that as a group we need to embrace it and use it to our advantage rather than shun it and pretend it does not exist
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I want this so bad (big fan of acetates and space)!!
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7/ A specific number of Generally Recognized as Safe (GRAS) items with carcinogenic signs is difficult to pinpoint because many are "self-certified" by companies without mandatory FDA review. However, recent analyses and research have identified dozens of GRAS or common food substances that exhibit carcinogenic behavior: 1) 25 Known Carcinogens: A recent analysis by the Environmental Defense Fund (EDF) identified 25 cancer-causing substances currently allowed in U.S. food, despite legal prohibitions against carcinogenic additives. These include formaldehyde, methylene chloride, and trichloroethylene. library.edf.org/AssetLink/02… 2) 6 Specific Preservatives: A study published in The BMJ followed 105,000 people and found that 6 GRAS-designated preservatives were associated with higher cancer risks: sodium nitrite, potassium nitrate, sorbates, potassium metabisulfite, acetates, and acetic acid. 3) 15 Flavoring Compounds: Research has noted that 15 flavor compounds previously approved as GRAS by industry panels showed carcinogenic signs in rodent studies. pubmed.ncbi.nlm.nih.gov/1215…

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I had one lecturer who just had a prepared stack of acetates, and he’d just put them up in order and read them. So we asked him for a copy, and then never bothered giving to those lectures 🙂
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Replying to @TGNCards
FREE USA 🇺🇸 S&H is included in any deal. Tom Selleck cards: take the trio $5 All 6 Bond actors Rittenhouse acetates graded by SGC: $65 2 UD NTTD inserts: $3 each Bonus incentive: buy the 6 Bond lot, I’ll give you the 2 inserts AND the Tom Selleck trio for free.
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