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Chemical Communications @ChemCommun
Joined March 2009
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Social media and connecting with our community – moving on from X. You can continue to find the latest news and updates from ChemComm on our other social media channels: Bluesky bsky.app/profile/chemcomm.rs… LinkedIn linkedin.com/showcase/chemco… rsc.org/news-events/articles…
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ICYMI, from @afukazawa79 and colleagues: 'Rethinking aromaticity of reduced thienoquinoids: insights from an S-Pechmann dye dianion' pubs.rsc.org/en/content/arti…

Rethinking aromaticity of reduced thienoquinoids: insights from an S-Pechmann dye dianion

A dianionic species of a thienoquinoid derivative bearing a cross-conjugated γ-thiolactone, the so-called S-Pechmann dye, has been synthesized and characterized. Comparative analysis with a pentafu...

pubs.rsc.org
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New from Ellen Matson and Zhou Lu: 'Consequences of substituting framework metals in polyoxometalates on H-atom uptake: proton-coupled electron transfer at a Keggin-type polyoxomolybdate' @MatsonLab pubs.rsc.org/en/content/arti…

Consequences of substituting framework metals in polyoxometalates on H-atom uptake: proton-coupled...

The proton-coupled electron transfer to the surface of a Keggin-type polyoxomolybdate, [nBu4N]3[PMo12O40], is described. The thermochemistry of surface O–H bonds generated upon reduction/protonation...

pubs.rsc.org
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ICYMI, from @ckerzig, @GloriusFrank and colleagues: 'Pushing the limit of triplet–triplet annihilation photon upconversion towards the UVC range' 🔥 #OpenAccess 🔓 pubs.rsc.org/en/content/arti…

Pushing the limit of triplet–triplet annihilation photon upconversion towards the UVC range

Triplet–triplet annihilation photon upconversion (TTA-UC) provides a milder alternative to traditional UVB/UVC photochemistry. However, suitable sensitizer-annihilator pairs are scarce, in particular...

pubs.rsc.org
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New review article from Anna Slater and colleagues at @LivUni: 'Self-assembly under continuous flow conditions' pubs.rsc.org/en/content/arti…

Self-assembly under continuous flow conditions

Self-assembly plays a crucial role in the formation of hierarchical supramolecular structures and functional materials. The use of flow chemistry for self-assembly processes has garnered significant...

pubs.rsc.org
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ICYMI, from @Faguang_Zhang and colleagues at Tianjin University: 'Transition metal/photocatalyst-free skeletal editing of indene with iodonium difluorodiazo reagent to access 2-(difluoromethyl)naphthalene' pubs.rsc.org/en/content/arti…

Transition metal/photocatalyst-free skeletal editing of indene with iodonium difluorodiazo reagent...

In this study, we design and synthesize a reactive difluorodiazo hypervalent iodine(III) reagent that facilitates the ring expansion of indene under mild basic conditions at room temperature. This...

pubs.rsc.org
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ICYMI, from Tomoyuki Mochida and colleagues at @KobeU_PR 'Solvent-free photochemical formation of cubane-type Ru complexes from organometallic ionic liquids with cyanoborate anions' pubs.rsc.org/en/content/arti…

Solvent-free photochemical formation of cubane-type Ru complexes from organometallic ionic liquids...

Coordination compounds, including cage compounds, are typically synthesized via solution reactions. Here, we report the solvent-free, quantitative conversion of organometallic ionic liquids (ILs)...

pubs.rsc.org
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ICYMI, from Kiyosei Takasu, Hiroshi Takikawa and colleagues at Kyoto University: Take a look at 'Arylative double bond transposition of allylic alcohols via silicon-tethered intramolecular benzyne–ene reactions' @KUGousei pubs.rsc.org/en/content/arti…

Arylative double bond transposition of allylic alcohols via silicon-tethered intramolecular...

Silicon-tethered intramolecular benzyne–ene reactions provide an efficient strategy for converting allylic alcohols into aryl-substituted homoallylic alcohol derivatives. This approach utilizes a...

pubs.rsc.org
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Check out this new article from Filipp Furche, William Evans and colleagues at @UCIChemistry on the four-electron oxidation and one-electron reduction of a bis(terphenylthiolate) U(ii) complex. pubs.rsc.org/en/content/arti… '

Four-electron oxidation and one-electron reduction of the bis(terphenylthiolate) U(II) complex,...

The utility of the sterically bulky terphenylthiolate ligand, (SAriPr6)1− in expanding uranium reductive chemistry has been explored. Reduction of U(SAriPr6)2I forms the U(ii) complex, U(SAriPr6)2,...

pubs.rsc.org
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ICYMI, from @mvdelius, Fedor Jelezko, Alexander Kuehne and co. 'Carbazole-functionalized Chichibabin diradicaloids with redshifted absorption and enhanced photoluminescence' 🔥 #OpenAccess 🔓 pubs.rsc.org/en/content/arti…

Carbazole-functionalized Chichibabin diradicaloids with redshifted absorption and enhanced photol...

Organic radicals and diradicaloids that are both stable and luminescent are promising candidates for molecular qubits in quantum technologies. Here we report two new carbazole-functionalized Chichi...

pubs.rsc.org
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New from Clare Mahon and colleagues at @DurhamChemistry 'An unexpected chlorination of an organic sunscreen' #OpenAccess 🔓 pubs.rsc.org/en/content/arti…

An unexpected chlorination of an organic sunscreen

The origin of intense red staining on fabrics contaminated by sunscreen and treated with bleach has been attributed to an unexpected dichlorination of a common UV filter. The structure of the...

pubs.rsc.org
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ICYMI, from @sjgharpure and colleagues at @iitbombay 'Lewis acid-promoted cascade reactions of cyclopropenes: a unified approach to stereoselective synthesis of cyclic ethers and oxaspirolactones' pubs.rsc.org/en/content/arti…

Lewis acid-promoted cascade reactions of cyclopropenes: a unified approach to stereoselective...

Lewis acid-promoted 5/6-exo trig hydroalkoxylation/reduction cascade of ω-hydroxy cyclopropenes gave expeditious, stereoselective access to THF/THP derivatives. Monoester substituted ω-hydroxy...

pubs.rsc.org
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New from @PutlaSudarsanam and colleagues: 'Catalytic imidazolysis of PET plastic waste using self-assembled NbOx nanorods' @SP_Heterocat buff.ly/Ipb0kyc
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New from Tomoyuki Mochida and colleagues at @KobeU_PR 'Solvent-free photochemical formation of cubane-type Ru complexes from organometallic ionic liquids with cyanoborate anions' buff.ly/UfGCJQG
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New from @SharmaLabOU 'Iron-catalyzed iodonium ion promoted activation of conventional thioglycosides for stereoselective 1,2-cis furanosylations' #OpenAccess 🔓 buff.ly/qTgYW65
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New Review article from @gregory_chatel 'Scaling-up green chemistry: bridging innovation and industrial applications' buff.ly/JGivCEe
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New from @Debdas_snu and colleagues: 'Charge transfer alteration and white light emission in photochromic triphenylamine-norbornadiene-triazine switch' #OpenAccess 🔓 buff.ly/9eMWniw
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New from @afukazawa79 and colleagues: 'Rethinking aromaticity of reduced thienoquinoids: insights from an S-Pechmann dye dianion' pubs.rsc.org/en/content/arti…

Rethinking aromaticity of reduced thienoquinoids: insights from an S-Pechmann dye dianion

A dianionic species of a thienoquinoid derivative bearing a cross-conjugated γ-thiolactone, the so-called S-Pechmann dye, has been synthesized and characterized. Comparative analysis with a pentafu...

pubs.rsc.org
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ICYMI, from @CharlieFehl and Arun Thangarasu at @waynestatechem 'Thioglycoside functionalization via chemoselective phosphine acceleration of a photocatalytic thiol–ene reaction' #OpenAccess 🔓 pubs.rsc.org/en/content/arti…

Thioglycoside functionalization via chemoselective phosphine acceleration of a photocatalytic...

Thioglycosides are enzymatically stable carbohydrate variants used in biotechnology as probes and investigational drugs. To date, harsh activation conditions limit the scope of thiol–ene sugar...

pubs.rsc.org
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New Hot article from @ckerzig @GloriusFrank and colleagues: 'Pushing the limit of triplet–triplet annihilation photon upconversion towards the UVC range' 🔥 #OpenAccess 🔓 buff.ly/pd5P9tz

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