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KenTanaka-Maeda_Lab @KenTanaka_Lab
Joined September 2021
  • Tweets 91
  • Following 71
  • Followers 709
9 Photos and videos
Our recent work has been published in Angew. Chem. Int. Ed. “Enantioselective Synthesis of Axially Chiral Diaryl Ethers via Rhodium-Catalyzed [2 2 2] Cycloaddition” doi.org/10.1002/anie.3486845
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Our recent review has been published in ACS Catal. “Parallel Kinetic Resolution of Racemic Compounds Using a Single Chiral Catalyst” doi.org/10.1021/acscatal.6c0…
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Our recent work is published in Nature Communications. “Partially π-exposed 3D carbohelicene for mechanical tuning of conductance and thermopower in single-molecule junctions” doi.org/10.1038/s41467-026-7…
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巨大なπ拡張ヘリセンが金電極との間で安定な単一分子接合を形成し、機械的変形によって熱電能や電気伝導性が変化することを実験的に実証しました。こちらの研究に関して、東京科学大学からプレスリリースを行っています！ isct.ac.jp/ja/news/thttqzmcq… ktanaka-cap.mac.titech.ac.jp…

単一分子接合で熱電能を機械的に制御 | Science Tokyo - 東京科学大学

isct.ac.jp
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Our recent work is published in Angew. Chem. Int. Ed. “Rh-Catalyzed Chemodivergent Parallel Kinetic Resolution and Desymmetrization of Enynes and Dienynes with Acrylamides” doi.org/10.1002/anie.9965825
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Our recent work is published in Org. Lett. "Visible-Light-Driven Silylation of C(sp2)–O Bonds with Silylboranes via Nickel Catalysis" doi.org/10.1021/acs.orglett.…

Visible-Light-Driven Silylation of C(sp2)–O Bonds with Silylboranes via Nickel Catalysis

Developing a general and efficient method for C(sp2)–O bond silylation that tolerates broad silyl groups under mild conditions remains a key challenge. Here, we report that naphthol and phenol...

pubs.acs.org
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Our recent work is published in Org. Lett. "Enantioselective Construction of Fluorinated Tertiary Stereocenters by Rh-Catalyzed [2 2 2] Cycloaddition of 1,6-Enynes with α-Fluoroacrylamides" doi.org/10.1021/acs.orglett.…

Enantioselective Construction of Fluorinated Tertiary Stereocenters by Rh-Catalyzed [2 2 2]...

We report the enantioselective construction of fluorinated tertiary stereocenters via [2 2 2] cycloaddition between 1,6-enynes and α-fluoroacrylamides using a chiral cationic Rh(I) catalyst at...

pubs.acs.org
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D2佐藤くんが第71回有機金属化学討論会(9/17〜19)においてポスター賞を受賞しました。おめでとうございます！ PA-32 Atropselective Synthesis of Diaryl Ethers by Rh-Catalyzed [2 2 2] Cycloaddition
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M1市村くんが第35回基礎有機化学討論会(9/9〜11)においてポスター賞を受賞しました。おめでとうございます！ 2P025 段階的な歪み構築による多層積層型ヘリカルナノグラフェンの合成
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M2清水くんが第56回構造有機化学若手の会 夏の学校においてポスター賞を受賞しました。おめでとうございます！ 不斉[2 2 2]付加環化反応を経由した多重ヘリカルナノグラフェンの立体選択的合成
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D2河合くんが第88回有機合成化学協会関東支部シンポジウムにおいて優秀発表賞を受賞しました。おめでとうございます！ B09 分子内[2 2 2]付加環化反応によるキラル[2.2]シクロファンの不斉合成
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D2印南さんが第88回有機合成化学協会関東支部シンポジウムにおいて優秀発表賞を受賞しました。おめでとうございます！ B08 柔軟な 1,6-ジインを用いた[2 2 2]付加環化反応によるテトラアリールベンゼンの合成
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Our recent work is published in Chem. Commun. "Spiro-fluorene-indenoindenyl-Ir(I) complex-catalyzed, 1,3-azole-directed C(sp3)–H borylation with pinacolborane" doi.org/10.1039/D5CC03115J
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Our recent work in Chem. Commun. has been featured on the Front cover! pubs.rsc.org/en/content/arti…
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Our recent work is published in ACS Catal. "Rh-Catalyzed [2 2 2] Cycloaddition between Aryl-Substituted 1,6-Diynes and Monoynes: Controlling Alkyne Reactivity with Hexafluoroisopropanol" doi.org/10.1021/acscatal.5c0…

Rh-Catalyzed [2 2 2] Cycloaddition between Aryl-Substituted 1,6-Diynes and Monoynes: Controll...

The transition metal-catalyzed [2 2 2] cycloaddition between aryl-substituted 1,6-diynes and monoynes is a valuable transformation for synthesizing π-conjugated compounds. The formation of...

pubs.acs.org
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Our recent work is published in Org. Lett. “Rh-Catalyzed in Situ Generation of Phenanthrocyclobutadienes from Tetraaryl-Diynes and Their Cycloadditions with Cycloalkenediones and o-Chloranil” doi.org/10.1021/acs.orglett.…

Rh-Catalyzed in Situ Generation of Phenanthrocyclobutadienes from Tetraaryl-Diynes and Their...

We have developed a method for the catalytic in situ generation of Rh(I)-phenanthrocyclobutadiene complexes from a cationic Rh(I)/Segphos complex and tetraaryl-diynes. These complexes can undergo...

pubs.acs.org
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Our recent work is published in Angew. Chem. “Rhodium-Catalyzed Intermolecular Arylative [2 2 1] Annulation-Oxidation to Produce Electron-Deficient Azulene-Embedded Polycyclic Aromatic Hydrocarbons” doi.org/10.1002/anie.2025056…
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D2佐藤くんが日本化学会第105春季年会学生講演賞を受賞しました。おめでとう！F2101-1am-04 ロジウム触媒を用いた[2 2 2]付加環化反応による軸不斉ジアリールエーテルの不斉合成
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Assoc. Prof. Chihiro Maeda, Asst. Prof. Juntaro Nogami, and Dr. Takashi Yamazaki have joined our lab. Stay tuned for more updates from our team!
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昨日4/1付で前田千尋准教授および野上純太郎助教が新たに着任されました。また、本年1月より山崎孝先生にも研究室に加わっていただいております。 新体制でさらに研究を加速してまいります。今後ともどうぞよろしくお願いいたします！
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