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RompelGroup @RompelLab

Welcome to @RompelLab @univienna working on #cyanobacteria, new #metallo #proteins & #polyoxometalate compounds for protein #crystallization & #catalysis!

Joined November 2017
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#CuNews No.644: 🚀 New study alert! Liaocheng University report: In Situ Synthesis of Cu-CP by Cleavage of the C–N Bond for CO2 Fixation into Oxazolidinones through Aziridine/Propargylamine under Ambient Conditions in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

In Situ Synthesis of Cu-CP by Cleavage of the C–N Bond for CO2 Fixation into Oxazolidinones through...

The conversion of CO2 into high-value chemicals under mild conditions offers the advantages of atom economy, bond-formation efficiency, and product complexity. Among the transformations, coupling...

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#CuNews No.643: 🚀 New study alert! University of Oklahoma report: Rb4CuSb2Cl11 and Rb2In0.91(0.2)Sb0.09Cl5·H2O: Wide Band Gap 0D Metal Halide Semiconductors in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Rb4CuSb2Cl11 and Rb2In0.91(0.2)Sb0.09Cl5·H2O: Wide Band Gap 0D Metal Halide Semiconductors

Herein, we report the discovery, structural and photophysical characterization of a new zero-dimensional (0D) lead-free all-inorganic halide, Rb4CuSb2Cl11, which adopts a new structure type. Single...

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#CuNews No.642: 🚀New study alert! Moscow State University report: Buckle-Layered, Decorated Square-Kagome System KCu7BiO4(SO4)5in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Buckle-Layered, Decorated Square-Kagome System KCu7BiO4(SO4)5

We report the gas-transport synthesis, crystal structure, and magnetic properties of the buckle-layered KCu7BiO4(SO4)5, which enriches few in number the family of decorated square-kagome systems...

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#CuNews No.641: 🚀 New study alert! University of Ljubljana report: Influence of La Doping on the Magnetic Properties of the Two-Dimensional Spin-Gapped System SrCu2(BO3)2in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Influence of La Doping on the Magnetic Properties of the Two-Dimensional Spin-Gapped System...

Doping of the two-dimensional dimer antiferromagnet SrCu2(BO3)2 has long been proposed as a potential route toward realizing resonating valence bond superconductivity in this system; however,...

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#CuNews No.640: 🚀 New study alert! Hubei University report: Anionic Supramolecular Cluster with [Cu4Br7O]2– Core: Self-Assembly and Photocatalysis for Organic Transformations in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Anionic Supramolecular Cluster with [Cu4Br7O]2– Core: Self-Assembly and Photocatalysis for Organic...

The design and development of photoactive cuprous halide cluster catalysts have attracted considerable attention in photocatalysis. Herein, we report the rational design of a cationic tripodal ligand...

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#CuNews No.639: 🚀 New study alert! Noncalcined Pillared Cu1-MCoM Bimetallic–Organic Framework as Bifunctional Electrocatalyst for Urea-Assisted Hydrogen Production in Seawater in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Noncalcined Pillared Cu1-MCoM Bimetallic–Organic Framework as Bifunctional Electrocatalyst for...

The urea oxidation reaction (UOR) provides an energy-efficient mechanism for H2 generation from urea-rich wastewater while also supporting environmental remediation efforts. The current research...

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#CuNews No.638: 🚀 New study alert! Kyoto University report: Roles of Labile #Copper Coordinated by Histidine in Reductive Inactivation of Copper Efflux Oxidase in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Roles of Labile Copper Coordinated by Histidine in Reductive Inactivation of Copper Efflux Oxidase

Copper efflux oxidase (CueO) is involved in copper homeostasis in Escherichia coli by catalyzing the oxidation of cuprous ion (Cu ) to cupric ion (Cu2 ). CueO has been studied as a direct electron...

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#POMNews No.227: 🚀New study alert! Crystal Structure Elucidation of Reduced Dawson-Type #Polyoxometalates Guides Sustainable Fabrication of Ag/Graphene Nanocomposites with Catalytic Performance in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Crystal Structure Elucidation of Reduced Dawson-Type Polyoxometalates Guides Sustainable Fabricat...

The structural elucidation of highly reduced polyoxometalates (POMs) and their structure–reducibility relationships have persisted as pivotal challenges in materials chemistry, driven by their...

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#CuNews No.637: 🚀New study alert! North-Eastern Hill Uni: Aggregation-Induced Emission and Thermally Activated Delayed Fluorescence in Sterically Encumbered Copper(I) Complexes of Diphosphine and Substituted Phenanthroline Ligands in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Aggregation-Induced Emission and Thermally Activated Delayed Fluorescence in Sterically Encumbered...

In this work, two heteroleptic and one homoleptic copper(I) complex using bisphosphine and diimine ligands are reported. Single-crystal X-ray analysis provided insight into the solid packing due to...

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#CuNews No.636: 🚀 New study alert! University of Calcutta report: Cytotoxic Effects of Mono- and Trinuclear Platinum(II)–N-Heterocyclic Carbene Complexes against Triple-Negative Breast Cancer Cell Lines in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Cytotoxic Effects of Mono- and Trinuclear Platinum(II)–N-Heterocyclic Carbene Complexes against...

Platinum(II) complexes with N-heterocyclic carbene (NHC) ligands have been demonstrated as intriguing and promising foundations to construct novel metal-based anticancer drugs. To the best of our...

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#CuNews No.635: 🚀New study alert! China West Normal University: Incorporation of #Cu2 into Mn3O Cluster-Based MOF for Catalytic Carboxylative Cyclization of Propargylic Amines with Flue Gas CO2 To Synthesize Oxazolidinones in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Incorporation of Cu2 into Mn3O Cluster-Based MOF for Catalytic Carboxylative Cyclization of...

Efficient transformation of flue gas CO2 is of great significance, but it remains a formidable challenge. Herein, we constructed four isostructural metal–organic frameworks (MOFs) with anionic...

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#POMNews No.226: 🚀 New study alert! Northeastern University of China report: A Vanadium-Based #Polyoxometalate Nanozyme for 2-Mercaptobenzothiazole Colorimetric Detection and Visible-Light-Driven Degradation in Water in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

A Vanadium-Based Polyoxometalate Nanozyme for 2-Mercaptobenzothiazole Colorimetric Detection and...

As a notorious pollutant in water, 2-mercaptobenzothiazole (MBTZ) severely endangers environmental safety and human survival. In this respect, MBTZ detection and removal are urgently required. For...

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#CuNews No.634: 🚀 New study alert! University de Sherbrooke report: Design of a Triple Emissive #Cu4I4 Coordination Polymer through Ligand Engineering in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Design of a Triple Emissive Cu4I4 Coordination Polymer through Ligand Engineering

Through rational ligand design, the coordination polymer 1D-[Cu4(μ3-I)4(μ2-L1)2]n (CP1; L1 = 1,1-(1′-naphthylthio)methane) has been predictably prepared from CuI and L1 in acetonitrile where both the...

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#CuNews No.633: 🚀 New study alert! University of Texas report: Trinuclear #Copper(I) and Silver(I) Complexes of a Pentafluorosulfanyl-Decorated Pyrazolate in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Trinuclear Copper(I) and Silver(I) Complexes of a Pentafluorosulfanyl-Decorated Pyrazolate

This study reports the synthesis and characterization of the first fluorinated coinage metal pyrazolates with SF5 groups, specifically {[3-(SF5)Pz]M}3 (M = Cu, Ag), and compares them to trifluorome...

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#CuNews No.632: 🚀 New study alert! Zhejiang Normal University report: CH4 Purification by a Carborane-Based Metal–Organic Framework with Rare Tetranuclear #Copper Nodes in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

CH4 Purification by a Carborane-Based Metal–Organic Framework with Rare Tetranuclear Copper Nodes

The development of efficient methane (CH4) purification technology from natural gas is crucial to its utilization. Adsorptive separation using porous metal–organic frameworks (MOFs) offers a promis...

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#CuNews No.631: 🚀 New study alert! Qingdao University report: Sn-Induced Stable Cu in #Cu2O/Cu6Sn5 Interface System for Stabilizing *OCHO in CO2-to-Formate Electroreduction in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Sn-Induced Stable Cu in Cu2O/Cu6Sn5 Interface System for Stabilizing *OCHO in CO2-to-Formate...

The rational construction of Cu-based interface with stable Cu species is crucial in CO2 electroreduction reactions. Herein, a Sn-induced Cu2O/Cu6Sn5 interface system (denoted as Cu2O/CuSn) with...

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#CuNews No.630: 🚀 New study alert! Indian Institute of Technology Ropar report: #Cu(I)-Anchored NHC-Functionalized Covalent Organic Framework (COF) for Catalyzing CO2 Chemical Fixation into High-Value Compounds in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Cu(I)-Anchored NHC-Functionalized Covalent Organic Framework (COF) for Catalyzing CO2 Chemical...

Rapid urbanization has intensified global energy demands, leading to elevated carbon dioxide emissions. Therefore, capturing and utilizing CO2 as a C1 feedstock is a viable way to synthesize value-...

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#CuNews No.629: 🚀 New study alert! 🚀 Nikolaev Institute of Russia report: Bimetallic Rh/Ir–Cu Metastable Nanoalloys as Promising Catalysts for Propane Prereforming in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Bimetallic Rh/Ir–Cu Metastable Nanoalloys as Promising Catalysts for Propane Prereforming

In the present work, we synthesized and characterized new complex compounds, [Rh(NH3)5Cl][Cu(H2O)(C2O4)2], [Ir(NH3)5Cl][Cu(H2O)(C2O4)2], and [RhxIr1–x(NH3)6]2[Cu(H2O)(C2O4)2]2[Cu(H2O)2(C2O4)2]·2H2O...

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#CuNews No.628: 🚀 New study alert! 🚀 University of Oklahoma report: Structural Diversity and Tunable Emission in Hybrid Organic–Inorganic Copper(I) Bromides in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Structural Diversity and Tunable Emission in Hybrid Organic–Inorganic Copper(I) Bromides

Recently, hybrid organic–inorganic copper(I) metal halides have attracted global attention due to their intriguing optical properties and low-cost solution processability. In this work, we report...

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#CuNews No.627: 🚀 New study alert! 🚀 Fuzhou University report: Electronic Structure Engineering of Pd–Cu Alloy Catalysts for Enhanced Methanol Electrooxidation in @InorgChem 😃more: doi.org/10.1021/acs.inorgche…

Electronic Structure Engineering of Pd–Cu Alloy Catalysts for Enhanced Methanol Electrooxidation

The widespread application of direct methanol fuel cells (DMFCs) is limited by the sluggish kinetics of the anodic reaction, the high cost of catalysts, and their susceptibility to poisoning....

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