Palladium‐Catalyzed Alkyl Amination of Olefins via Radical‐Polar Crossover at Room Temperature
We disclosed a palladium-catalyzed tandem radical Heck/allylic amination of α-bromoamides with 1,3-butadienes and enynes at room temperature to yield γ-lactams. Unlike previous alkyl Heck reactions,...
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