May 19
Al（アルミニウム）錯体のNBSブロモ化に関する論文がChemRxivに掲載されました！最大で18ブロモ化を達成し、単離、結晶構造解析までできました。共同研究者に感謝🙏
Post-synthetic Bromination of a Dinuclear Aluminum Helicate and Its Chiroptical Properties | ChemRxiv chemrxiv.org/doi/full/10.264…
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2,570
Feb 13
We are pleased to have Dr. R. Arunachalam, RIL, Vadodara, presenting a talk on "Development of Helicate Catalysis for sustainable organic synthesis" Their expertise in helicate 🧬 catalysis will be very informative and insightful.
#ICCIEE #CSIRCSMCRI
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Feb 8
「和楽器”つなぐ”コンサート」へ
出がけの雪がそれなりだったで迷いましたが、熱気たっぷりの演奏楽しかった！
小湊さんの、鹿の遠音→Helicateというギャップ、お見事でした(｡˃ ᵕ ˂ ﾉﾉ"
櫻木さんの耳なし芳一、もっと聴きたかったなー
無事に帰宅。会場で買ってきた焼き芋食べて温まります♪
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27 Oct 2025
#supramolecular helicates bind DNA junctions by induced-fit too! Exploring how helicate size, shape and symmetry affect structures of #DNAjunctions @J_A_C_S
pubs.acs.org/doi/10.1021/jac…
Congrats @SJ_Dettmer, Hugo, @SBajpaihere @HannonGroup @UoBChemistry @MIBTP_BBSRC @uob_bear
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4,827
23 Oct 2025
A Flexible Quadruple-Stranded Helicate Demonstrates a Strong Binding Preference for DNA Three-Way Junctions by Induced Fit | Journal of the American Chemical Society pubs.acs.org/doi/10.1021/jac…
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3,912
Electropolymerization of Silver(I) Helicate into Conductive Metallopolymer: Structural and Functional Insights | Inorganic Chemistry pubs.acs.org/doi/10.1021/acs… Wałęsa-Chorab and co-workers @InorgChem #silver #helicate #electropolymerization #conductive #colors
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578
2 Sep 2025
Molecular Qubit Gets a Supramolecular Armor, Extending Coherence in Solids Without Compromising Control. Trapping a spin inside a helicate cage frees it from decoherence’s grip- quantum liberty through confinement.
EPR reveals doubled relaxation times, paving way for scalable quantum devices.
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84
15 Aug 2025
#OnTheCover Light-Driven Ratchet Mechanism Accelerates Regioselective Metal-Cation Exchange in a Heterobimetallic Helicate (Larissa K. S. von Krbek and co-workers) onlinelibrary.wiley.com/doi/… @vkrbek @UniBonn • onlinelibrary.wiley.com/doi/…
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5,973
18 Jun 2025
A new JACS paper by our collaborators reports on an aluminum-based dinuclear triple-stranded helicate, so-called ALPHY, revealing dynamic excited-state localization induced by Jahn–Teller distortion via coherent vibrational spectroscopy. pubs.acs.org/doi/abs/10.1021…
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1,616
12 Jun 2025
(4/4) Crucially, the Zn-helicate can #regioselectively exchange one Zn(II) for Fe(II), forming a Zn-Fe helicate. This process is significantly accelerated by #LightIrradiation via the #MolecularRatchet mechanism, reminiscent of the operation of a claw machine.
#SystemsChemistry
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1,880
25 May 2025
WASABI 2025 spring tour
WASABIの4人 中村卓也さん
W津軽三味線で聴き応え満点💯
しぐれとイエロージーナのコラボꕤ*
そしてWASABIメンバーと奏でる中村卓也さん作曲の遊園も素晴らしかったです✧*。
HelicateやKOKIRIKOまでコラボでめちゃ楽しいライブでした♡ᩚ
素敵な笑顔のお二人📸
#WASABI4
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25 May 2025
WASABI 2025
spring tour
at.姫路 DOUBLE KING CAFE
姫路公演はスペシャルゲストで
津軽三味線・中村卓也さんが登場🪕
セトリ 5/25
✽アガイティーラ
✽紅蓮
✽AOI
✽歩み
✽しぐれ
✽イエロージーナ
✽遊園
✽Helicate
✽峯雲
✽escape
✽Open the Door
✽KOKIRIKO
アンコール
✽烈光
#WASABI4
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10 Apr 2025
Happy to share our @HannonGroup @samdettmer99 @hooper_cat publication in Angewandte Chemie, showcasing the use of a cancer cell-overexpressed enzyme as a switch for non-canonical DNA structure recognition by a metallo-supramolecular triple-helicate...onlinelibrary.wiley.com/doi/…
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25
8 Oct 2024
Brief interlude from parental leave to share Jamie Allen’s article on Fe2, Co2, Zn2 helicate complexes with dinucleating bis(SacNac) ligands - just accepted in @DaltonTrans pubs.rsc.org/en/content/arti…
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2,882
17 Sep 2024
Please do not forget to read our recent publication on Crucial Role of bite angle in influencing helicate formation in Fe(II) complexes based on Oxa/thiadiazole ligands and their spin state choices with @RCreixenti #acs #CGD #postdoc
pubs.acs.org/doi/full/10.102…
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1,853
13 Sep 2024
Hierarchical Self-Assembly Promoted Circularly Polarized Luminescence Enhancement and Handedness Inversion of Metal–Organic Helicate
12 Sep 2024
Hierarchical Self-Assembly Promoted Circularly Polarized Luminescence Enhancement and Handedness Inversion of Metal–Organic Helicate chinesechemsoc.org/doi/10.31…
#chemistry #openaccess #science #chemtwitter
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2,055
13 Sep 2024
Hierarchical Self-Assembly Promoted Circularly Polarized Luminescence Enhancement and Handedness Inversion of Metal–Organic Helicate
12 Sep 2024
Hierarchical Self-Assembly Promoted Circularly Polarized Luminescence Enhancement and Handedness Inversion of Metal–Organic Helicate chinesechemsoc.org/doi/10.31…
#chemistry #openaccess #science #chemtwitter
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1,944
13 Sep 2024
Hierarchical Self-Assembly Promoted Circularly Polarized Luminescence Enhancement and Handedness Inversion of Metal–Organic Helicate
12 Sep 2024
Hierarchical Self-Assembly Promoted Circularly Polarized Luminescence Enhancement and Handedness Inversion of Metal–Organic Helicate chinesechemsoc.org/doi/10.31…
#chemistry #openaccess #science #chemtwitter
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2,253
13 Sep 2024
Hierarchical Self-Assembly Promoted Circularly Polarized Luminescence Enhancement and Handedness Inversion of Metal–Organic Helicate
12 Sep 2024
Hierarchical Self-Assembly Promoted Circularly Polarized Luminescence Enhancement and Handedness Inversion of Metal–Organic Helicate chinesechemsoc.org/doi/10.31…
#chemistry #openaccess #science #chemtwitter
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2,233
12 Sep 2024
Hierarchical Self-Assembly Promoted Circularly Polarized Luminescence Enhancement and Handedness Inversion of Metal–Organic Helicate chinesechemsoc.org/doi/10.31…
#chemistry #openaccess #science #chemtwitter
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