Research group @BUChemistry interested in catalysis, organic synthesis, organometallic chemistry, and electrochemical methods.

Joined February 2023
34 Photos and videos
22 Dec 2025
Congrats to @Yahuiiiiiiii and Siyuan on their Perspective in ACS Electrochemistry! We highlight strategies over the last ~10 years in Shono-type functionalization from tunable conditions to mediators, outlining exciting prospects for further development. pubs.acs.org/doi/full/10.102…
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Derosa Lab retweeted
20 Dec 2025
This is a really nice example of selectivity emerging from constraint, not just energetics. The Co–O–C interaction looks less like a secondary stabilisation and more like a geometric gate in configuration space, effectively collapsing the accessible pathways so the Z-product becomes the only coherent reconstruction. In that light, the DFT isn’t just explaining selectivity after the fact; it’s revealing a structure-first control mechanism, where redox mediation and MS-PCET act to maintain the constraint rather than drive the outcome. That’s an interesting direction for thinking about scalability and robustness in catalytic design. @derosalab @uclachem @ACSCatalysis
19 Dec 2025
We are thrilled to see our collaborative work with the Gutierrez group at @uclachem published in @ACSCatalysis today! Congrats to @bryanparnitzke and team on an impressive study! More to come in this area soon, building on exciting mechanistic insights. pubs.acs.org/doi/10.1021/acs…
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And a (laughably big) paper cake to celebrate! feat. Director's Cut TOC image
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Derosa Lab retweeted
Fantastic visit at @UniofNottingham School of Chemistry today sharing some of our recent work in @derosalab using voltage control to enable selective electrosynthesis and catalysis. Thanks to @miriamoduill for the gracious hosting and organizing great discussions with faculty!
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27 Jun 2025
We are grateful to the @acsprf for funding our proposal on arene functionalization strategies for upconversion of aromatic feedstocks! Congrats to all the awardees this cycle: cen.acs.org/acs-news/ACS-Boa…
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Derosa Lab retweeted
Congrats to Brett and Jillian on this incredibly powerful e-SNAr strategy! Synthetically enabling, extremely robust, and highly energy-efficient with as low as 20 mW of power at 50 mmol scale with a proposed uphill ET-promoted redox chain mechanism. Dump, stir, ⚡️ #chemtwitter
28 May 2025
SNAr powers the engine of drug discovery and production, but electronic demands restrict access to important chemical space. We describe an e-SNAr strategy to bridge this gap that operates under air at RT with catalytic charge, simplifying scalability. chemrxiv.org/engage/chemrxiv…
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28 May 2025
SNAr powers the engine of drug discovery and production, but electronic demands restrict access to important chemical space. We describe an e-SNAr strategy to bridge this gap that operates under air at RT with catalytic charge, simplifying scalability. chemrxiv.org/engage/chemrxiv…
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26 May 2025
Harnessing reduced Fe in electrocatalysis faces many challenges with respect over-reduction and catalyst instability. In this preprint, we describe a redox mediator strategy to tame a (P3P)Fe(I) species for semi-hydrogenation of alkynes as a model study: chemrxiv.org/engage/chemrxiv…
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Huge congrats to our very own @bryanparnitzke for being awarded the NSF Graduate Research Fellowship! We are so proud of you! 🎉🥳 #chemtwitter #nsfgrfp
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19 Mar 2025
San Diego, here we come! For anyone interested in what we've been up to, please consider stopping by one of our talks next week at ACS Spring 2025! #ACSSpring2025 #chemtwitter
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24 Feb 2025
Congrats to Bryan on a fantastic qualifying examination! We are so proud of you! #newPI #phdlife #chemtwitter
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Derosa Lab retweeted
SAXITOXIN simplified: Appearing today in @ChemRxiv is a short, highly scalable, convergent approach to this entire natural product family using a tactical combination of radical retrosynthesis, biocatalysis (in collaboration with Merck), and C–H functionalization logic: chemrxiv.org/engage/chemrxiv…
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12 Feb 2025
Congrats to our FIRST PhD Candidate, Leyla, on passing her qualifying exam with flying colors! We are so proud of you! #newPI #echem #phdlife
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17 Jan 2025
With the Gutierrez group @UCLA , we report a unique mode of electrocatalytic semi-hydrogenation to generate Z-alkenes using a redox mediator strategy. Distortion analyses by DFT reveal a distinct origin of stereoselectivity. Exciting times ahead! chemrxiv.org/engage/chemrxiv…
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17 Jan 2025
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17 Jan 2025
Amazing to collaborate with the legendary @Gutierrez_Lab !!
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